In the Morin Lab, we investigate emergent structures and dynamics of soft materials self-assembled from microscopic constituents.
We aim at understanding how specific properties of the building blocks, such as shape or self-propulsion, translate into involved macroscopic properties. We focus in particular on studying synthetic active materials and seek to unveil the mechanisms leading to genuine non-equilibrium properties. Examples of such materials include population of colloidal rollers forming flocks and 3-dimensional sediments of colloidal particles. If you are interested in knowing more about our research, you're welcome to drop us a message!
Colloidal vortex self-assembled from active colloidal particles.
Video is real time. Particles are 5 µm diameter. Vortex is 1 mm diameter.
Marine Le Blay
Master Student 2021/2022
Visiting Master Student
Ecole Normale Supérieure de Lyon
Marlise van der Veen
Visiting Master Student
---- Samadarshi will give a talk and present his PhD work on Active Matter.
---- Alexandre will give a talk and present some latest results on Flocking.
---- Alexandre has contributed with a talk on fluids of oscillators.
---- Marine will present her latest work on Active Matter.
---- Marine has contributed with a soundbite talk.
- Repulsive torques alone trigger crystallization of constant speed active particles, Marine Le Blay and Alexandre Morin, Soft Matter, 2022,18, 3120-3124,
Rapid characterization of neutral polymer brush with a conventional zetameter and a variable pinch of salt,
Mena Youssef, Alexandre Morin, Antoine Aubret, Stefano Sacanna, and Jérémie Palacci,
Soft Matter, 2020,16, 4274-4282,
The fundamental and practical importance of particle stabilization has motivated various characterization methods for studying polymer brushes on particle surfaces. In this work, we show how one can perform sensitive measurements of neutral polymer coating on colloidal particles using a commercial zetameter and salt solutions. By systematically varying the Debye length, we study the mobility of the polymer-coated particles in an applied electric field and show that the electrophoretic mobility of polymer-coated particles normalized by the mobility of non-coated particles is entirely controlled by the polymer brush and independent of the native surface charge, here controlled with pH, or the surface–ion interaction. Our result is rationalized with a simple hydrodynamic model, allowing for the estimation of characteristics of the polymer coating: the brush length L, and the Brinkman length ξ, determined by its resistance to flows. We demonstrate that the Debye layer provides a convenient and faithful probe to the characterization of polymer coatings on particles. Because the method simply relies on a conventional zetameter, it is widely accessible and offers a practical tool to rapidly probe neutral polymer brushes, an asset in the development and utilization of polymer-coated colloidal particles.
Colloidal flocks in challenging environments,
Directed collected motion within herds, swarms and flocks, is a phenomenon that takes place at all scales in living systems. Physicists have rationalized the emergence of such collective behavior. They have described these systems as active materials. These materials are assembled from self-propelled units that spontaneously move in the same direction. By experimentally studying synthetic flocks, this work uncovers some properties of polar active materials in situations that disfavor their self-organization: their dynamics in disordered environments and their response to external perturbations. Colloidal rollers with alignment interactions are confined within microfluidic devices. At high density, they spontaneously form a flock which is characterized by the emergence of orientational long-ranged order. These colloidal flocks are prototypical realizations of polar active matter. We have studied the response of a polar active liquid assembled from colloidal rollers. We have shown that they display a hysteretic response to longitudinal perturbations. We have theoretically accounted for this non-linear behavior. We have used this behavior to realize autonomous microfluidic oscillators. We have also studied the dynamics of colloidal flocks that propagate through heterogeneous environments. Randomly positioned obstacles focalize flocks along favored channels that form a sparse and tortuous network. Increasing disorder leads to the destruction of flocks. We have demonstrated that the suppression of collective motion is a discontinuous transition generic to all polar active materials.
Flowing active liquids in a pipe: Hysteretic response of polar flocks to external fields,
Alexandre Morin and Denis Bartolo,
Phys. Rev. X 8, 021037,
We investigate the response of colloidal focks to external fields. We first show that individual colloidal rollers align with external flows as would a classical spin with magnetic fields. Assembling polar active liquids from colloidal rollers, we experimentally demonstrate their hysteretic response: confined colloidal flocks can proceed against external flows. We theoretically explain this collective robustness, using an active hydrodynamic description, and show how orientational elasticity and confinement protect the direction of collective motion. Finally, we exploit the intrinsic bistability of confined active flows to devise self-sustained microfluidic oscillators.
Sounds and hydrodynamics of polar active fluids,
Delphine Geyer, Alexandre Morin and Denis Bartolo,
Spontaneously flowing liquids have been successfully engineered from a variety of biological and synthetic self-propelled units. Together with their orientational order, wave propagation in such active fluids have remained a subject of intense theoretical studies for more than two decades. Until now, this phenomenon has however never been experimentally observed. Here, we establish and exploit the propagation of sound waves in colloidal active materials with broken rotational symmetry. We show that two mixed modes coupling density and velocity fluctuations propagate along all directions in colloidal-roller fluids. We then show how the six materials constants defining the linear hydrodynamics of these active liquids can be measured from their spontaneous fluctuation spectrum, while being out of reach of conventional rheological methods. This active-sound spectroscopy is not specific to synthetic active materials and could provide a quantitative hydrodynamic description of herds, flocks and swarms from inspection of their large-scale fluctuationsHighlighted by:
Diffusion, subdiffusion, and localization of active colloids in random post lattices,
Alexandre Morin, David Lopes Cardozo, Vijayakumar Chikkadi, and Denis Bartolo,
Phys. Rev. E 91, 042611,
Combining experiments and theory, we address the dynamics of self-propelled particles in crowded environments. We first demonstrate that motile colloids cruising at constant speed through random lattices undergo a smooth transition from diffusive, to subdiffusive, to localized dynamics upon increasing the obstacle density. We then elucidate the nature of these transitions by performing extensive simulations constructed from a detailed analysis of the colloid-obstacle interactions. We evidence that repulsion at a distance and hard-core interactions both contribute to slowing down the long-time diffusion of the colloids. In contrast, the localization transition stems solely from excluded-volume interactions and occurs at the void-percolation threshold. Within this critical scenario, equivalent to that of the random Lorentz gas, genuine asymptotic subdiffusion is found only at the critical density where the motile particles explore a fractal maze.
Distortion and destruction of colloidal flocks in disordered environments,
Alexandre Morin, Nicolas Desreumaux, Jean-Baptiste Caussin, and Denis Bartolo,
How do flocks, herds and swarms proceed through disordered environments? This question is not only crucial to animal groups in the wild, but also to virtually all applications of collective robotics, and active materials composed of synthetic motile units. In stark contrast, appart from very rare exceptions, our physical understanding of flocking has been hitherto limited to homogeneous media. Here we explain how collective motion survives to geometrical disorder. To do so, we combine experiments on motile colloids cruising through random microfabricated obstacles, and analytical theory. We explain how disorder and bending elasticity compete to channel the flow of polar flocks along sparse river networks akin those found beyond plastic depinning in driven condensed matter. Further increasing disorder, we demonstrate that collective motion is suppressed in the form of a first-order phase transition generic to all polar active materials.
Collective motion with anticipation: Flocking, spinning, and swarming,
Alexandre Morin, Jean-Baptiste Caussin, Christophe Eloy, and Denis Bartolo,
Phys. Rev. E 91, 012134,
We investigate the collective dynamics of self-propelled particles able to probe and anticipate the orientation of their neighbors. We show that a simple anticipation strategy hinders the emergence of homogeneous flocking patterns. Yet, anticipation promotes two other forms of self-organization: collective spinning and swarming. In the spinning phase, all particles follow synchronous circular orbits, while in the swarming phase, the population condensates into a single compact swarm that cruises coherently without requiring any cohesive interactions. We quantitatively characterize and rationalize these phases of polar active matter and discuss potential applications to the design of swarming robots.
Faculty of Science
Leiden Instituut Onderzoek Natuurkunde
LION - Biological & Soft Matter
Niels Bohrweg 2
Room number HL 10.02
2333 CA Leiden
+31 71 527 4091